MHAT and other outer-sphere reactions

99. Decagram-scale synthesis of GB13 and remodeling to the GB alkaloids

99. Freeman, S. M.; Landwehr, E. M.; Rojas, J. R.; Tanaka, R.; Bailey, J. B.; Gembicky, M.; Shenvi, R. A.* “Decagram-scale synthesis of GB13 and remodeling to the GB alkaloids” J. Am. Chem. Soc. 2026, 148, 41494–41501.

97. Enantioselective Cross-Coupling of an Unbiased Carbon Radical Enabled by Perfluoroaryl Semicorrin Ligands

97. Rojas, J. J.;† Aouane, F. A.;† Ramirez, L. S.;‡ Rentería-Gómez, Á.;‡ Zhang, Y.; Breaz, M. A.; van den Elsen, T.; Bailey, J. B.; Gembicky, M.; Gutierrez, O.;* Shenvi, R. A.* “Enantioselective Cross-Coupling of an Unbiased Carbon Radical Enabled by Perfluoroaryl Semicorrin Ligands” J. Am. Chem. Soc. 2026, 148, 41626–41638.

94. Iron-Catalyzed [1+1+1] Cyclopropanation via Stereoselective Ester Olefination

94. Kong, L.;‡ Zong, K.;‡ Hopfengärtner, M.; Orzolek, B. J.; Shenvi, R. A.* “Iron-Catalyzed [1+1+1] Cyclopropanation via Stereoselective Ester Olefination” Science 2026, 393, 910–916.

92. Cross- and branched-selective hydroalkenylation by metal hydride selection

92. Li, C., Gan, X., Yu, I., Smith, M.A., Shenvi, R.A. “Cross- and branched-selective hydroalkenylation by metal hydride selection“, Science, 2026, doi: 10.112.6/science.aeb2389

91. Synthesis of Modified Fusicoccane Diterpenoids via Diverging MHAT Reactivity

91. Snelson, D. W.; Fernandez, S. A.; Shenvi, R. A. “Synthesis of Modified Fusicoccane Diterpenoids via Diverging MHAT Reactivity”, Synthesis, 2025, doi: 10.1055/a-2744-6756

81. On the role of thermally activated EDA complexes in decarboxylative cross-coupling

81. Dao, N.; Shenvi, R. A. “On the role of thermally activated EDA complexes in decarboxylative cross-coupling” Tetrahedron [invited, T. Maimone award issue], 2024, 166, 134204.

80. Metal-Hydride C–C Cross-Coupling of Alkenes Through a Double Outer-Sphere Mechanism

80. Dao, N.; Gan, X.-c.; Shenvi, R. A. “Metal-Hydride C–C Cross-Coupling of Alkenes Through a Double Outer-Sphere Mechanism” [invited] J. Org. Chem. 2024, 89, 16106–16113.

77. Carbon Quaternization of Redox Active Esters and Olefins via Decarboxylative Coupling

77. Gan, X.-c.;† Zhang, B.;† Dao, N.;† Bi, C.; Pokle, M.; Kan, L.; Collins, M. R.; Tyrol, C. C.; Bolduc, P. N.; Nicastri, M.; Kawamata, Y.; Baran, P. S.; Shenvi, R. A. Carbon Quaternization of Redox Active Esters and Olefins via Decarboxylative Coupling. Science 2024, 384, 113. †co-first authors

76. Alkene hydrobenzylation by a single catalyst that mediates iterative outer-sphere steps

76. Kong, L.;† Gan, X.-c.;† van der Puyl-Lovett, V. A.;† Shenvi, R. A. Alkene hydrobenzylation by a single catalyst that mediates iterative outer-sphere steps. J. Am. Chem. Soc. 2024, 146, 2351. ChemRxiv 10.26434/chemrxiv-2023-zw9c2 2023, †co-first authors.

75. Inner- and outer-sphere cross-couplings for high Fsp3 fragments in natural product space

75. Kotesova, S.; Shenvi, R. A. Inner- and outer-sphere cross-couplings for high Fsp3 fragments in natural product space. Acc. Chem. Res. 2023, 56, 3089.