Metal hydride atom transfer (MHAT)

92. Cross- and branched-selective hydroalkenylation by metal hydride selection

92. Li, C., Gan, X., Yu, I., Smith, M.A., Shenvi, R.A. “Cross- and branched-selective hydroalkenylation by metal hydride selection“, Science, 2026, doi: 10.112.6/science.aeb2389

91. Synthesis of Modified Fusicoccane Diterpenoids via Diverging MHAT Reactivity

91. Snelson, D. W.; Fernandez, S. A.; Shenvi, R. A. “Synthesis of Modified Fusicoccane Diterpenoids via Diverging MHAT Reactivity”, Synthesis, 2025, doi: 10.1055/a-2744-6756

81. On the role of thermally activated EDA complexes in decarboxylative cross-coupling

81. Dao, N.; Shenvi, R. A. “On the role of thermally activated EDA complexes in decarboxylative cross-coupling” Tetrahedron [invited, T. Maimone award issue], 2024, 166, 134204.

77. Carbon Quaternization of Redox Active Esters and Olefins via Decarboxylative Coupling

77. Gan, X.-c.;† Zhang, B.;† Dao, N.;† Bi, C.; Pokle, M.; Kan, L.; Collins, M. R.; Tyrol, C. C.; Bolduc, P. N.; Nicastri, M.; Kawamata, Y.; Baran, P. S.; Shenvi, R. A. Carbon Quaternization of Redox Active Esters and Olefins via Decarboxylative Coupling. Science 2024, 384, 113. †co-first authors

76. Alkene hydrobenzylation by a single catalyst that mediates iterative outer-sphere steps

76. Kong, L.;† Gan, X.-c.;† van der Puyl-Lovett, V. A.;† Shenvi, R. A. Alkene hydrobenzylation by a single catalyst that mediates iterative outer-sphere steps. J. Am. Chem. Soc. 2024, 146, 2351. ChemRxiv 10.26434/chemrxiv-2023-zw9c2 2023, †co-first authors.

75. Inner- and outer-sphere cross-couplings for high Fsp3 fragments in natural product space

75. Kotesova, S.; Shenvi, R. A. Inner- and outer-sphere cross-couplings for high Fsp3 fragments in natural product space. Acc. Chem. Res. 2023, 56, 3089.

73. Iron-catalyzed hydrobenzylation: stereoselective synthesis of (–)-eugenial C

73. Gan, X.-c.;§ Kotesova, S.;§ Castanedo, A.; Green, S. A.; Møller, S. L. B.; Shenvi, R. A. Iron-catalyzed hydrobenzylation: stereoselective synthesis of (–)-eugenial C. J. Am. Chem. Soc. 2023, 145, 15714. §co-first authors

70. Manganese, iron and cobalt-catalyzed radical olefin hydrofunctionalization

70. van der Puyl, V. A.; Shenvi, R. A. Manganese, iron and cobalt-catalyzed radical olefin hydrofunctionalization Science of Synthesis, 2.14: Base Metal Catalysis, 2023, Ed. N. Yoshikai.

65. Stereodivergent attached ring synthesis via non-covalent interactions: a short formal synthesis of merrilactone

65. Huffman, B. J.; Chu, T.; Hanaki, Y.; Wong, J. J.; Chen, S.; Houk, K. N.; Shenvi, R. A. Stereodivergent attached ring synthesis via non-covalent interactions: a short formal synthesis of merrilactone A Angew. Chem. Int. Ed. 2022, 61, e202114514.

60. Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals

60. Shevick, S. L.; Wilson, C. V.; Kotesova, S.; Kim, D.; Holland, P. L.; Shenvi, R. A. Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals. Chem. Sci. 2020, 12401–12422.